Synthese et etude cristallochimique et magnetique des solutions solides LaxHo1−xB6
Identifieur interne : 004C84 ( Main/Exploration ); précédent : 004C83; suivant : 004C85Synthese et etude cristallochimique et magnetique des solutions solides LaxHo1−xB6
Auteurs : Abdellatif Berrada [France] ; Jean-Pierre Mercurio [France] ; Jean Etourneau [France] ; Paul Hagenmuller [France]Source :
- Materials Research Bulletin [ 0025-5408 ] ; 1976.
Abstract
Abstract: LaxHo1−xB6 solid solutions of CaB6 type have been prepared by borothermal reduction in the range 0.2 ⩽ x < 1. For LaHo+La < 0.2 the corresponding solid solution coexists with a HoB4 and HoB12 mixture. HoB6 could not be obtained : the ionic radius of Ho3+ seems to be a border value for the stability of the CaB6 structure. Extrapolation of the magnetic properties of LaxHo1−xB6 solid solutions allows to confer to an eventual HoB6 an interaction mechanism of the RKKY type.
Url:
DOI: 10.1016/0025-5408(76)90168-9
Affiliations:
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<front><div type="abstract" xml:lang="en">Abstract: LaxHo1−xB6 solid solutions of CaB6 type have been prepared by borothermal reduction in the range 0.2 ⩽ x < 1. For LaHo+La < 0.2 the corresponding solid solution coexists with a HoB4 and HoB12 mixture. HoB6 could not be obtained : the ionic radius of Ho3+ seems to be a border value for the stability of the CaB6 structure. Extrapolation of the magnetic properties of LaxHo1−xB6 solid solutions allows to confer to an eventual HoB6 an interaction mechanism of the RKKY type.</div>
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